Rhenium Nanostructures Loaded into Amino-Functionalized Resin as a Nanocomposite Catalyst for Hydrogenation of
Piotr Cyganowski1, Anna Dzimitrowicz2, Piotr Jamroz2
1Department of Process Engineering and Technology of Polymer and Carbonaceous Materials, Faculty of Chemistry, Wroclaw University of Science and Technology, 50-370 Wroclaw, Poland.
Abstract:
The present work presents a new nanocomposite catalyst with rhenium nanostructures (ReNSs) for the catalytic hydrogenation of 4-nitrophenol and 4-nitroaniline. The catalyst, based on an anion exchange resin with functionality derived from 1,1'-carboimidazole, was obtained in the process involving anion exchange of ReO4- ions followed by their reduction with NaBH4. The amino functionality present in the resin played a primary role in the stabilization of the resultant ReNSs, consisting of ≈1% (w/w) Re in the polymer mass. The synthesized and capped ReNSs were amorphous and had the average size of 3.45 ± 1.85 nm. Then, the obtained catalyst was used in a catalytic reduction of 4-nitrophenol (4-NP) and 4-nitroaniline (4-NA). Following the pseudo-first-order kinetics, 5 mg of the catalyst led to a 90% conversion of 4-NP with the mass-normalized rate constant (km1) of 6.94 × 10-3 min-1 mg-1, while the corresponding value acquired for 4-NA was 7.2 × 10-3 min-1 mg-1, despite the trace amount of Re in the heterogenous catalyst. The obtained material was also conveniently reused.
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