Confinement of MnO_x@Fe₂O₃ core-shell catalyst with titania nanotubes: Enhanced N₂ selectivity and SO₂ tolerance in...

Surface interface regulation is an important research content in the field of heterogeneous catalysis. To improve the interface interaction between the active component and matrix, tremendous efforts have been dedicated to tailoring the morphology, size, and structure of composite catalysts. In this work, we report a confinement strategy to synthesize a series of core-shell catalysts loaded with metal oxides on titania nanotubes (TNTs), which were applied to the selective catalytic reduction of NO_x with ammonia. Interestingly, the core-shell catalyst with confinement of TNTs exhibited the remarkable activity at low temperature region, N₂ selectivity and sulfur tolerance. Benefiting from the superior interfacial confinement characteristic of TNTs and Fe₂O₃, strong component interactions, the surface acid sites and strong oxidizability of MnO_x were properly regulated, thus obtained the outstanding activity, N₂ selectivity and provide chemical protection to effectively prevent SO₂ poisoning. As far as the reaction mechanism, we found that the adsorption and reactivity of Lewis acid sites were the dominant factors affecting the activity in the NH₃-SCR process by in situ DRIFT spectra. In general, our work provides an innovative strategy for constructing an TNTs-enwrapped nanocomposite with nano-confinement and core-shell structure to improve the low temperature SCR process.