Photocatalytic hydrogen evolution by degradation of organic pollutants over quantum dots doped nitrogen carbide

Semiconductor photocatalysts are of great importance for addressing current environmental and energy crises. In this study, we developed a simple exfoliation-sonication route to fabricate nitrogen carbide quantum dots (CNQDs) doped nitrogen carbide nanosheet (CNS) composite photocatalysts which were employed to produce hydrogen and degrade organic pollutants (methyl orange, acridine orange, aniline, and phenol) synchronously under visible light irradiation. The presence of acridine orange and aniline enhanced the hydrogen evolution efficiency from 8.8 mmol g^-1 h^-1 to 32.1 and 11.7 mmol g^-1 h^-1, respectively. On the contrary, methyl orange and phenol with the same concentration inhibited hydrogen evolution. Based on the proton chain and energy band analyses, the synchronous mechanism of photocatalytic hydrogen evolution and organic pollutant degradation on CNQDs/CNS was also proposed. On one side, the oxygen-containing functional groups on the surface of CNQDs and the surrounded water molecules constructed proton chains, increasing the combination probability between protons and photo-generated electrons. On the other side, the heterojunction of CNQDs/CNS induced the separation of photo-generated electron-hole pairs. The photo-generated electrons migrate to CNQDs, on which the protons were transformed into hydrogen molecules, while the holes migrated to CNS where the organic pollutants were oxidized synchronously.