Enhanced degradation of 2,6-dimethylphenol by photocatalytic systems using TiO₂ assisted with H₂O₂ and Fe(III)

In this study, several photocatalytic degradation systems were investigated using 2,6-dimethylphenol (2,6-DMP) as a model compound. Highly reactive species are formed in four systems, Fe(III), TiO₂, TiO₂/H₂O₂ and TiO₂/Fe(III) where complete degradation of 2,6-DMP was achieved under UV radiation. Photodegradation of the 2,6-DMP has been described by pseudo-first order kinetic model in the presence of TiO₂. In UV/TiO₂-H₂O₂ system, the addition of H₂O₂ in the TiO₂ suspension improves the degradation rate of 2,6-DMP from 70% to 100% for a H₂O₂ concentration of 10^-2 M in 3 h. In homogeneous system, HO^• and Fe²⁺ can be generated by the irradiation of Fe(III) solution. The speciation of Fe(III) obtained from Visual MINTEQ soft showed the formation of several species and Fe(OH)²⁺ were the most predominant and active species in a pH range of 2.5-3.5. At a low concentration of TiO₂ (30 mg L^-1), an important positive effect due to the iron addition has been shown in TiO₂/Fe(III) system, the entrance of metallic ions at different concentrations enhanced the photocatalytic activity of TiO₂. A degradation percentage of 90% was achieved in the UV/TiO₂-Fe(III) system under optimal conditions against 57% in UV/TiO₂ system. Strong synergistic effect was observed in the UV/TiO₂-H₂O₂ binary system. On the basis of literature, a pathway for 2,6-DMP degradation was proposed. The mechanism of degradation of the 2,6-DMP did not involve only HO^• radicals, an interaction of Fe(III) in the excited state with 2,6-DMP occurred giving rise to the formation of 2,6-dimethylphenoxyl radical.