Electronic Interaction between In Situ Formed RuO₂ Clusters and a Nanoporous Zn₃V₃O₈ Support and Its Use in the...

The catalytic activity and durability of RuO₂ clusters toward the oxygen evolution reaction (OER) are strongly associated with their support; however, how the electronic interaction would enhance the catalytic performance is still not quite clear. Herein, hierarchical nanoporous and single-crystal Zn₃V₃O₈ nanosheets are adopted to anchor in situ formed RuO₂ clusters. X-ray photoelectron analysis reveals significant binding energy changes of both Ru and V due to the creation of strong Ru-O-V bonding interaction, which would lead to the reconstruction of the electronic structure of the Zn₃V₃O₈ matrix and RuO₂ clusters. The ultrastrong electronic interaction also results in superior OER activity, indicated by a small overpotential at 10 mA cm^-2 (228 mV) and a shallow Tafel slope of 46 mV dec^-1. First-principles simulation further reveals the synergistic effect derived from the unique RuO₂@Zn₃V₃O₈ couple, which effectively regulates the electronic structure for the OER process. In addition, the created interfacial chemical bond and the confined microporous structure of the Zn₃V₃O₈ substrate could prevent the RuO₂ clusters from detachment and aggregation, making the nanocomposite a promising long-term stable OER electrocatalyst.