Tailoring Multiple Sites of Metal-Organic Frameworks for Highly Efficient and Reversible Ammonia Adsorption

The structural diversity and designability of metal-organic frameworks (MOFs) make these porous materials a strong candidate for NH₃ uptake. However, to achieve a high NH₃ capture capacity and good recyclability of MOFs at the same time remains a great challenge. Here, a multiple-site ligand screening strategy of MOFs is proposed for highly efficient and reversible NH₃ uptake for the first time. Based on the optimized DFT results for various possible ligands, pyrazole-3,5-dicarboxylate with multiple sites was screened as the best ligand to construct robust MOF-303(Al) with Al³⁺. It is experimentally found that the NH₃ adsorption capacity of MOF-303(Al) is as high as 19.7 mmol g^-1 at 25.0 °C and 1.0 bar, and the NH₃ capture is fully reversible and no clear loss of capture capacity is observed after 20 cycles of adsorption-desorption. Various spectral studies verify that the superior NH₃ capacity and excellent recyclability of MOF-303(Al) are mainly attributed to the hydrogen bonding interactions of NH₃ with multiple sites of MOF-303(Al).