Use of an automated respirometer for in situ chemical oxidation (ISCO) activator type and concentration selection

In situ chemical oxidation (ISCO) is a popular remediation technique for hydrocarbon-contaminated soil and groundwater. A range of oxidising agents and activators are available for ISCO; however, selection is usually based on contaminant destruction which is time-consuming and impacted by sample heterogeneity based on 1-10 g sample contaminant analysis. In this paper, we demonstrate the use of an automated respirometer, measuring CO₂ production, as a rapid and reliable approach for activator type and concentration selection. The approach is demonstrated based on tests in matrices of different types (loam soil and sand). In both matrices, CO₂ production was significantly increased following sodium persulphate (SPS) oxidation with iron activation in a concentration-dependant manner. Alkaline activation led to no increased CO₂ production compared to SPS addition without activation. The approach will provide greater confidence in treatability testing and reagent efficiency in ISCO projects.