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Updated: Oct 12, 2025

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Sodalite Cd66-Cage-Based Metal-Organic Framework Constructed by Cd9 and Cd5 Metal-Organic Clusters
Kecai Xiong1,2, Xin Li1, Yuwen Shi1
1School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu 221116, P. R. China.
Abstract:
A sodalite Cd66-cage-based metal-organic framework (MOF), namely, CPM-9S, has been constructed based on Cd9 and Cd5 metal-organic clusters (MOCs), which, to the best our knowledge, represents the first Cd-cage-based MOF that contains the highest-nuclear Cd-based MOC and the largest number of Cd2+ ions in a cage. The iodine adsorption performances in terms of the iodine adsorption capacity, adsorption isotherm, and adsorption kinetics, as well as the adsorption mechanism, have been further studied.
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