Wastewater post-coagulation sludge recycled as a multifunctional adsorbent via pyrolysis enhanced in carbon dioxide...

Massive wastewater post-coagulation sludge (WPCS) generated from the tertiary treatment facilities has been regarded as an environmentally burdensome waste. Herein, to take advantage of the abundant amounts of Al/Fe (hydr)oxides, the WPCS was converted into functional char via pyrolysis under CO₂ and N₂ atmosphere. The higher organic matter content and porous structure of WPCS than drinking water treatment sludge made it a more suitable precursor for biochar and adsorbent production. CO₂ expedited the thermolysis of the organics in WPCS and the Fe (hydr)oxides in WPCS further decreased the temperature of CO₂-mediated reaction. Therefore, the corresponding products outcompeted the chars in N₂, achieving ∼37% higher specific surface area, stronger aromaticity and more amorphous Al and Fe contents of 201.19 ± 2.25 and 27.03 ± 0.56 mg g^-1, accompanied by more loss of surface functional groups like carboxyl and hydroxyl. Accordingly, WPCS chars under CO₂ showed superior performance for removing phosphate (15.58 ± 0.19 mg g^-1), along with the adsorption of heavy metal (37.17 ± 1.25 mg g^-1 of Pb (II)) and dye (14.45 ± 0.11 mg g^-1 of methylene blue). In sum, this study proposes a win-win strategy to convert coagulation sludges into resources and a new candidate for multifunctional adsorbent production.