Related Experiment Video
Updated: Oct 12, 2025

Reducing Willow Wood Fuel Emission by Low Temperature Microwave Assisted Hydrothermal Carbonization
Published on: May 19, 2019
Degradation of urea-formaldehyde resin residues by a hydrothermal oxidation method into recyclable small molecular
Tianhang Ren1, Yan Wang2, Nan Wu3
1College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410000, China.
Abstract:
Urea-formaldehyde (UF) resin residues and the related product wastes as organic hazardous wastes are difficult to be biodegraded or recycled. In this research, a hydrothermal oxidation method using hydrogen peroxide (H2O2) solution has been developed for the degradation and recycling of UF resin residues. The effects of solution concentration, temperature, and time on the degradation efficiency and products of UF resin residues were studied. Under optimal conditions, i.e., 140 °C and 5 wt% H2O2 solution, over 75% of UF resin residues was degraded after 3 h. The degradation efficiency is much higher than that of the traditional hydrothermal treatment or acid hydrolysis method. In addition, results from Fourier transform infrared spectroscopy (FTIR), gas chromatography-mass spectroscopy (GC-MS), nuclear magnetic resonance spectroscopy (NMR), and X-ray diffraction (XRD) confirmed that H2O2 solution degrades UF resin residues to low molecular compounds, such as alcohols, methylal, and amides. This research provides a novel and high-efficient hydrothermal oxidization process for the degradation of UF resin residues, which might be a promising environmentally friendly and low-cost method for the disposal and recycling of industrial UF resin residues.
Related Concept Videos
Preparation of Aldehydes and Ketones from Alcohols, Alkenes, and Alkynes
Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
Environmental Applications of Microorganisms
Hydroboration-Oxidation of Alkenes
Hydrolysis
Hydrolysis is a chemical reaction in which the addition of water breaks down a polymer into its simpler monomer units. For example, peptides break into amino acids, carbohydrates into simple sugars, and DNA into nucleotides. Enzymes often facilitate these processes.
Hydrolysis Reverses Dehydration Synthesis
Complex carbohydrates can be broken down by breaking the bonds between individual sugar units. The reaction breaks a glycosidic bond as water is added to the compound. The...

