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Updated: Oct 12, 2025
A Facile Synthetic Method to Obtain Bismuth Oxyiodide Microspheres Highly Functional for the Photocatalytic Processes of Water Depuration
Published on: March 29, 2019
Anchoring bismuth oxybromo-iodide solid solutions on flexible electrospun polyacrylonitrile nanofiber mats for
Shuai Liu1, Pingping Liang2, Jie Liu2
1Center for Advanced Optoelectronic Functional Materials Research, and Key Laboratory of UV Light-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, 5268 Renmin Street, Changchun 130024, People's Republic of China; College of Science, Northeast Electric Power University, 169 Changchun Street, Jilin 132012, People's Republic of China.
Abstract:
Constructing floating photocatalysts with highly efficient visible-light utilization is a promising approach for practical photocatalytic wastewater treatment. In this study, we anchored bismuth oxybromo-iodide (BiOBrxI1-x (0 ≤ x ≤ 1)) on flexible electrospun polyacrylonitrile (PAN) nanofiber mats to create BiOBrxI1-x@PAN nanofibers with tunable light absorption properties as floating photocatalysts at room temperature. As x increased, the photocatalytic activity of the BiOBrxI1-x@PAN nanofibers with similar loading content initially increased, and then decreased, for the degradation of bisphenol A (BPA) and methyl orange (MO) under visible-light irradiation (λ > 420 nm) conditions. The BiOBrxI1-x@PAN (0 < x < 1) nanofibers exhibited better photocatalytic performance compared to the BiOBr@PAN and BiOI@PAN nanofibers. Under visible-light irradiation, the BPA degradation rate of the BiOBr0.5I0.5@PAN nanofibers was 1.9 times higher than that of the BiOI@PAN nanofibers, while the BiOBr@PAN nanofibers had no noticeable degradation performance. The MO degradation rate of the BiOBr0.5I0.5@PAN nanofibers was 2.5 and 3.2 times higher than that of the BiOBr@PAN and BiOI@PAN nanofibers, respectively. The enhanced performance possibly originated from a balance between the light absorption and redox capabilities, along with efficient separation of electron-hole pairs in the BiOBr0.5I0.5@PAN nanofibers, as determined by ultraviolet-visible diffuse reflectance spectroscopy, X-ray photoelectron spectra analysis of the valence bands, and photocurrent response characterization. Compared to the powder structures, the BiOBrxI1-x@PAN nanofibers showed enhanced performance due to the excellent dispersion and immobilization of the BiOBrxI1-x solid solution, which provided more active sites during photocatalytic degradation. In addition, their flexible self-supporting structures allowed for floating photocatalysis near the water surface. They could be reused directly without separation and maximized the absorption of visible light during the photocatalytic reaction. Therefore, these solid-solution-based floatable nanofiber photocatalysts are good potential candidates for wastewater treatment applications.
