Sustainable bioconversion of potato peel wastes into ethanol and biogas using organosolv pretreatment

Potato processing industries generate considerable amounts of residues, i.e., potato peel wastes (PPW). Valorization of PPW for bioethanol and biogas production via a biorefining process was investigated in this study. Organosolv pretreatment was performed on the PPW using 50-75% (v/v) ethanol solution at 120-180 °C with/without the presence of 1% (w/w) H₂SO₄ (as a catalyst). After the pretreatment, the solvent, i.e., ethanol, was recovered by distillation. Catalyzed organosolv pretreatment using 50% (v/v) ethanol at 120 °C followed by enzymatic hydrolysis resulted in a high hydrolysate yield of 539.8 g glucose/kg dry PPW that was successfully fermented to 224.2 g ethanol/kg dry PPW. To recover more energy, the liquid fraction of the pretreatment remained after solvent recovery and the unhydrolyzed solids that remained from the enzymatic hydrolysis were anaerobically digested. From each kg of dry PPW, the anaerobic digestion produced 57.9 L biomethane. Thus, the biorefinery comprising ethanolic organosolv pretreatment, solvent recovery, enzymatic hydrolysis, ethanolic fermentation, and anaerobic digestion of residues was produced 8112 kJ energy per kg of dry PPW.