High-responsivity, self-driven visible-near infrared Sb₂Se₃ nanorod array photodetector

Anisotropic antimony selenide (Sb₂Se₃) semiconductor has received considerable attention due to its unique one-dimensional crystal structure and corresponding superior and anisotropic optical and electronic properties. It is a promising material for a wide range of applications related to electronics and optoelectronics. Herein, we demonstrate a high-performance and self-powered Sb₂Se₃ nanorod array-based core/shell heterojunction detector fabricated on glass substate. The detector shows a wide spectral photoresponse range from visible to near-infrared (405-980 nm). The detector yields a detectivity of as high as 2.06×10¹² Jones in the visible light (638 nm) and that of 1.82×10¹² Jones (830 nm) at zero bias. Due to the strong built-in filed and excellent carrier transport, the detector exhibits ultrafast response speed at both rise (30 μs) and decay (68 μs) processes. Further analysis demonstrates that the noise is mainly generated from the 1/f noise in the low frequency range, while it is affected by the shot noise and generation-recombination noise in high frequency.