Efficient removal of U(VI) in acidic environment with spent coffee grounds derived hydrogel

In this study, humic-like substances (HLSs) was extracted from spent coffee grounds (SCGs), and it together with poly acrylic acid (PAA), was used for the first time to synthesize hydrogel material, namely HLSs/PAA gel, by one-step radical polymerization. Its maximum theoretical sorption capacity toward U(VI) at pH 3.00 was 661.01 mg/g, and it could decrease the concentration of U(VI) in acidic actual groundwater from 0.2537 to 0.0003 mg/L, showing that the gel had excellent U(VI) removal efficiency in acidic environment. The SEM characterization of HLSs/PAA gel showed that its macroporous network structure maintained well after the sorption process, indicating that the gel had excellent acid-resistant property. Moreover, the gel exhibited excellent anti-interference performance in the interfering ions effect experiment. The gel integrates the merits of excellent U(VI) sorption properties, stability and anti-interference performance in acidic environment, and has promising application prospects in the remediation of acidic uranium wastewater.