[Novel adsorption material for solid phase extraction in sample pretreatment of plant hormones]

Plant hormones (PHs) are of significance in plant growth, as they regulate the various processes related to plant growth, development, and resistance. Sensitive and precise quantitative analysis of PHs is a bottleneck in plant science research. Currently, liquid chromatography-tandem mass spectrometry is used for the accurate and efficient detection of PHs. Sample pretreatment is an indispensable step in the chromatography-mass spectrometry analysis of PHs because it directly affects the sensitivity and accuracy of subsequent detection methods. Among various pretreatment methods for PHs, solid phase extraction (SPE) is the most widely used. Various new types of SPE, such as dispersive SPE, magnetic SPE, and solid phase microextraction, have been developed by modifying the extraction cartridge. The choice of adsorption material is the key factor in the abovementioned SPE methods, which has a decisive effect on the extraction, purification, and enrichment effects of the target substance in the sample pretreatment process. Carbon-based materials, including carbon nanotubes, graphene, carbon and nitrogen compounds, as well as organic frameworks, including metal organic frameworks and covalent organic materials, are suitable adsorption materials because of their designable structure, large specific surface area, and good stability. Molecularly imprinted polymers and supramolecular compounds show specific molecular recognition based on host-guest interactions, which can significantly improve the selectivity of sample pretreatment methods. In this paper, SPE-related technology and the abovementioned types of functionalized adsorption materials in the pretreatment of PHs prevalent in the past five years have been reviewed. The related development trends are also summarized.