Constructing Schottky junctions via Pd nanosheets on DUT-67 surfaces to accelerate charge transfer

The separation, transfer and recombination of charge often affect the rate of photocatalytic reduction of CO₂. Schottky junctions can promote the rapid separation of space charge. Therefore, in this paper, Pd nanosheets were grown on the surface of DUT-67 by a hydrothermal method, and a Schottky junction was constructed between DUT-67 and Pd. Under the action of the Schottky junction, the CO yield of 0.3-Pd/DUT-67 reached 12.15 μmol/g/h, which was 17 times higher than that of DUT-67. Efficient charge transfer was demonstrated in photochemical experiments. The large specific surface area and the increased light utilization rate also contributed to the increase in the CO₂ reduction efficiency. In addition, the mechanism of Pd/DUT-67 photocatalytic reduction of CO₂ was proposed.