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Published on: March 24, 2019
Spin fluctuations yield zT enhancement in ferromagnets
Md Mobarak Hossain Polash1,2, Daryoosh Vashaee1,2
1Department of Materials Science and Engineering, NC State University, Raleigh, NC 27606, USA.
Spin fluctuations (SF) significantly enhance thermoelectric performance. This study reports an 80% increase in the thermoelectric figure-of-merit (zT) in ferromagnetic CrTe due to SF, a crucial finding for advanced thermoelectric materials.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Thermoelectrics
Background:
- Thermoelectric materials convert heat to electricity.
- Spin fluctuations (SF) are known to influence thermopower.
- Enhancement of the thermoelectric figure-of-merit (zT) by SF remained unproven.
Purpose of the Study:
- To demonstrate and quantify the enhancement of zT by SF in a ferromagnetic material.
- To investigate the impact of SF on electron and phonon transport.
- To provide a fundamental understanding for designing spin-driven thermoelectrics.
Main Methods:
- Experimental synthesis and characterization of ferromagnetic CrTe.
- Measurement of field-dependent thermoelectric transport properties (thermopower, thermal conductivity).
- Analysis using theoretical models to explain observed phenomena.
Main Results:
- Nearly 80% enhancement in zT observed in CrTe near 335 K due to SF.
- External magnetic fields suppressed thermopower enhancement and increased thermal conductivity, confirming SF's role.
- Experimental data showed good agreement with theoretical models.
Conclusions:
- Spin fluctuations are crucial for significantly enhancing thermoelectric figure-of-merit (zT).
- Ferromagnetic CrTe exhibits substantial zT enhancement driven by SF.
- This work paves the way for developing high-performance spin-driven thermoelectric devices.
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