Oxidation-absorption process for simultaneous removal of NO_x and SO₂ over Fe/Al₂O₃@SiO₂ using vaporized H₂O₂

3% Fe/Al₂O₃ and 3% Fe/Al₂O₃@SiO₂ were prepared to investigate the performance in simultaneous removal of NO_x and SO₂ using vaporized H₂O₂. Certain paraments were changed to explore the activity of catalysts, including temperature, H₂O₂ concentration, GHSV and coexistence gases component. A 24-h durability test was conducted on 3% Fe/Al₂O₃@SiO₂. Moreover, a series of characterizations were employed to analyze the physical and chemical properties of catalysts, including XRD, BET, SEM, TEM, FTIR and XPS. Compared with 3% Fe/Al₂O₃, 3% Fe/Al₂O₃@SiO₂ exhibited more excellent catalytic activity, which could achieve the peak removal efficiency of 100% for SO₂ and 93.76% for NO_x. Moreover, 3% Fe/Al₂O₃@SiO₂ kept stable simultaneous removal efficiency in a 24-h test. The characterization results indicated that the BET area was greatly improved and the core-shell structure was synthesized with the formation of more micropores and mesopores by the coating of SiO₂, which could improve the activity of catalyst at high temperature and high SO₂ concentration. Besides, the mechanism of SO₂ molecules on simultaneous removal was investigated. On one hand, a part of H₂O₂ was consumed by SO₂ molecules without catalyst, which resulted in the drop of NO_x removal by the decrease of oxidants. The main products were sulfites and bisulfites, which were broken down into SO₂ over the catalyst. On the other hand, the presence of SO₂ was beneficial for NO_x removal by increasing oxygen vacancies on the catalyst surface and facilitating the absorption of NO₂ by NaOH solution.