A review of microwave-assisted advanced oxidation processes for wastewater treatment

Microwave (MW) technology has gained increasing interest in wastewater treatment due to its unique properties, such as fast and uniform heating, hot spots effect, and non-thermal effect. MW enhances the production of active radicals (e.g., OH, SO₄^-), which exerts a stronger integrated treatment effect in combination with advanced oxidation processes. Over the years, microwave-assisted advanced oxidation processes (MW-AOPs) have developed rapidly to degrade pollutants as innovative treatment approaches. This paper provides a detailed classification and a comprehensive review of MW-AOPs. The latest applications of MW in different advanced oxidation systems (oxidation systems, catalytic oxidation systems, and photochemical, electrochemical and sonochemical systems) are reviewed. The reaction parameters and performance of MW-AOPs in wastewater treatment are discussed, and the enhancement of pollutant degradation by MW is highlighted. In addition, the operating costs of MW-AOPs are evaluated. Some recommendations on MW-AOPs are made for future research. This review provides meaningful information on the potential development and evolution of MW-AOPs.