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Updated: Oct 12, 2025

Hydrogen Production and Utilization in a Membrane Reactor
Published on: March 10, 2023
An Enhanced Sherwood Number to Model the Hydrogen Transport in Membrane Steam Reformers
Maria Anna Murmura1, Chiara Rocchetti1, Maria Cristina Annesini1
1Dipartimento di Ingegneria Chimica Materiali Ambiente, Sapienza Università di Roma, Via Eudossiana 18, 00184 Roma, Italy.
Abstract:
It is well known that membrane reactors are inherently two-dimensional systems in which species concentrations vary as a consequence of both the reaction and permeation across the membrane, which occurs in the direction perpendicular to that of the main gas flow. Recently, an expression for an enhanced Sherwood number was developed to describe the hydrogen concentration gradients arising in methane steam-reforming membrane reactors as a consequence of the combined effect of hydrogen production, dispersion, and permeation. Here, the analysis is developed in further detail with the aim of (i) assessing the validity of the simplifying assumptions made when developing the 1D model and (ii) identifying the operating conditions under which it is possible to employ the 1D model with the enhanced Sherwood number.
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