High-Stability Silver Nanowire-Al₂O₃ Composite Flexible Transparent Electrodes Prepared by Electrodeposition

Silver nanowire (AgNW) conductive film fabricated by solution processing was investigated as an alternative to indium tin oxide (ITO) in flexible transparent electrodes. In this paper, we studied a facile and effective method by electrodepositing Al₂O₃ on the surface of AgNWs. As a result, flexible transparent electrodes with improved stability could be obtained by electrodepositing Al₂O₃. It was found that, as the annealing temperature rises, the Al₂O₃ coating layer can be transformed from Al₂O₃·H₂O into a denser amorphous state at 150 °C. By studying the increase of electrodeposition temperature, it was observed that the transmittance of the AgNW-Al₂O₃ composite films first rose to the maximum at 70 °C and then decreased. With the increase of the electrodeposition time, the figure of merit (FoM) of the composite films increased and reached the maximum when the time was 40 s. Through optimizing the experimental parameters, a high-stability AgNW flexible transparent electrode using polyimide (PI) as a substrate was prepared without sacrificing optical and electrical performance by electrodepositing at -1.1 V and 70 °C for 40 s with 0.1 mol/L Al(NO₃)₃ as the electrolyte, which can withstand a high temperature of 250 °C or 250,000 bending cycles with a bending radius of 4 mm.