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Effect of Fe(III)-modified montmorillonite on arsenic oxidation and anthracene transformation in soil
Qi Li1, Xinhui Sun1, Wenjun Zhang1
1Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria, Tianjin Key Laboratory of Environmental Remediation and Pollution Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China.
Abstract:
Studies have shown that Fe(III)-modified montmorillonite can oxidize arsenite (As(III)) and also degrade anthracene. However, the application of Fe(III)-modified montmorillonite to remediate soil contaminated by arsenic and/or polycyclic aromatic hydrocarbons (PAHs) has not been reported. In this study, we first investigated the transformation of arsenic and anthracene on the surface of Fe(III)-modified montmorillonite, and then added Fe(III)-modified montmorillonite to spiked soil to examine its effect on arsenic oxidation and anthracene transformation. The experiments included treatments with As(III) and anthracene added separately or combined (both at a rate of 100 mg/kg). Compared with Na-modified montmorillonite, Fe(III)-modified montmorillonite significantly promoted As(III) oxidation and anthracene transformation on its surface. After 15 days of incubation, the proportion of As(V) (As(V)/[As(III) + As(V)]) on Na-modified montmorillonite was approximately 60%, and the transformation extent of anthracene was < 30%; on Fe(III)-modified montmorillonite, on the other hand, the proportion of As(V) was approximately 90%, and almost all anthracene was transformed. Adding 5% Fe(III)-modified montmorillonite to spiked soil also significantly enhanced As(III) oxidation and anthracene transformation. After 15 days, in the soil with added Fe(III)-modified montmorillonite, the proportion of As(V) was approximately 40%, the transformation extent of anthracene was > 60%, and approximately half of the initial added anthracene was transformed to anthraquinone. By contrast, after 15 days, in the soil without added Fe(III)-modified montmorillonite, the proportion of As(V) was only approximately 20%, the transformation extent of anthracene was < 25%, and anthraquinone was not detected. In both the montmorillonite and soil systems, the transformation of arsenic and anthracene had little influence on each other. The results showed that Fe(III)-modified montmorillonite has the potential to remediate soil contaminated by arsenic and PAHs.
