Development of sludge-based activated char sorbent with enhanced hydrophobicity for oil spill cleanup

Recovery of oil spilled on surface waters by the use of sorbents remains one of the primary oil spill response options available. To improve on this response measure, we have successfully fabricated an activated char (AC) sorbent material by pyrolysis of sewage sludge (SS), a readily available waste product generated across the world from wastewater treatment plants. The inherent Fe-minerals in SS texture were converted to magnetic Fe₃O₄ particles during the pyrolysis reaction. The AC provided a unique means to recover the sorbent after the oil sorption process with a magnetic field. Meanwhile, a superhydrophobic sorbent material with a water contact angle of 152.2° was created by the treatment of AC with myristic acid which could float on the water surface. Feasibility studies at the laboratory-scale were conducted with motor oil and light crude oil to evaluate its potential use in spill response operations. Results showed a sorption capacity of about 8.5 and 10.7 g/g for motor oil and light crude oil, respectively. Following the recovery of the test oils by ethanol stripping, the material could be recycled up to 5 times with trivial loss in sorption capacity. This research proposes a framework for the development of a highly efficient sorbent material for oil spill response operations from SS waste.