Structural and Chemical Properties of Geopolymer Gels Incorporated with Neodymium and Samarium

The present work was focused on doping of 1% and 5% both of Nd₂O₃ and Sm₂O₃ in geopolymer gels. One of the main goals was to determine the influence of the behavior of Nd and Sm as dopants and structural nanoparticles changes of the final geopolymer formed. It is shown that the disorder formed by alkali activation of metakaolin can accommodate the rare earth cations Nd³⁺ and Sm³⁺ into their aluminosilicate framework structure. The main geopolymerization product identified in gels is Al-rich (Na)-AS-H gel comprising Al and Si in tetrahedral coordination. Na⁺ ions were balancing the negative charge resulting from Al³⁺ in tetrahedral coordination. The changes in the structures of the final product (geopolymer/Nd₂O₃; Sm₂O₃), has been characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) analysis with energy dispersive spectrometry (EDS). Nucleation at the seed surfaces leads to the formation of phase-separated gels from rare earth phase early in the reaction process. It is confirmed that Nd and Sm have been shown to form unstable hydroxides Nd(OH)₃ and Sm(OH)₃ that are in equilibrium with the corresponding oxides.