Hybrid electrons in the trimerized GaV₄O₈

Mixed-valent transition-metal compounds display complex structural, electronic and magnetic properties, which often intricately coexist. Here, we report the new ternary oxide GaV₄O₈, a structural sibling of skyrmion-hosting lacunar spinels. GaV₄O₈ contains a vanadium trimer and an original spin-orbital-charge texture that forms upon the structural phase transition at T_S = 68 K followed by the magnetic transition at T_N = 35 K. The texture arises from the coexistence of orbital molecules on the vanadium trimers and localized electrons on the remaining vanadium atoms. Such hybrid electrons create opportunities for novel types of spin, charge, and orbital order in mixed-valent transition-metal compounds.