Antioxidation Mechanism of Highly Concentrated Electrolytes at High Voltage

It has been researched that highly concentrated electrolytes (HCEs) can solve the problem of the excessive decomposition of dilute electrolytes at a high voltage, but the mechanism is not clear. In this work, the antioxidation mechanism of HCE at a high voltage was investigated by in situ electrochemical tests and theoretical calculations from the perspective of the solvation structure and physicochemical property. The results indicate that compared with the dilute electrolyte, the change of solvation structures in HCE makes more PF₆^- anions easier to be oxidized prior to the dimethyl carbonate solvents, resulting in a more stable cathode-electrolyte interphase (CEI) film. First, the lower oxidation potential of the solvation structure with more PF₆^- anions inhibits the side effects of the electrolyte effectively. Second, the CEI film, consisted of LiF and LiPOF generated from the oxidation of PF₆^- and Li₃PO₄ generated from the hydrolysis of LiPF₆ via the soluble PO₂F₂^- intermediate, can reduce the interface impedance and improve the conductivity. Intriguingly, the high viscosity of HCEs and the hydrolysis of LiPF₆ are proven to play a positive role in enhancing the interfacial stability of the electrolyte/electrode at a high voltage. This study builds a deep understanding of the bulk and interface properties of HCEs and provides theoretical support for their large-scale application in high-voltage battery materials.