Subcritical water hydrolysis coupled with hydrothermal carbonization for apple pomace integrated cascade valorization

This study evaluates an integrated biorefinery approach based on the waste hierarchy for the valorization of biodegradable waste, focusing on apple processing residues. Firstly, subcritical water hydrolysis was investigated at different experimental conditions (temperature 80 to 120 °C, dilution factor 10 to 30, residence time 10 to 30 min, initial pressure 10 to 30 bar) with the coincident aim of dissolving fermentable sugars and assess the effects of such treatment on the downstream solids. Secondly, spent solids were further processed by hydrothermal carbonization in the same reactor at fixed conditions (i.e., 180 °C, 3 h). The results showed that not only up to nearly 500 g kg_db^-1 of sugars are dissolved but also lignocellulosic structure is amended, improving products valorization potential. Depending on pretreatment conditions, the proposed approach can deliver hydrochar with potential either as soil amendment or for long-term applications, sustainably valorizing food waste.