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Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles
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Metallic core-shell nanoparticles for conductive coatings and printing
Anna Pajor-Świerzy1, Krzysztof Szczepanowicz1, Alexander Kamyshny2
1Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Niezapominajek 8, 30-239 Kraków, Poland.
Advances in Colloid and Interface Science
|December 5, 2021
Summary
This review covers core-shell bimetallic nanoparticles, using conductive copper or nickel cores with noble metal shells like silver or gold. These nanoparticles offer stability and are key for conductive coatings and printed electronics.
Area of Science:
- Materials Science
- Nanotechnology
- Electrochemistry
Background:
- Bimetallic nanoparticles offer unique properties by combining different metals.
- Low-cost, conductive metals like copper (Cu) and nickel (Ni) are desirable for core materials.
- Noble metals like silver (Ag) and gold (Au) provide excellent oxidation resistance for shells.
Purpose of the Study:
- To review synthesis methods for core-shell bimetallic nanoparticles.
- To evaluate the oxidation stability of these nanoparticles under various conditions.
- To explore their application in conductive formulations, coatings, and printed electronics.
Main Methods:
- Chemical synthesis approaches for nanoparticle formation.
- Physical synthesis techniques for nanoparticle fabrication.
- Combined chemical and physical methods for optimized synthesis.
Main Results:
- Successful synthesis of core-shell nanoparticles with Cu/Ni cores and Ag/Au shells.
- Demonstrated oxidation stability of core-shell structures in diverse environments.
- Development of conductive compositions utilizing these nanoparticles.
Conclusions:
- Core-shell bimetallic nanoparticles provide a stable and conductive material solution.
- These nanoparticles are suitable for advanced applications in conductive coatings.
- The reviewed synthesis strategies enable tailored properties for printed electronics.

