Synthesis, surface activities and aggregation properties of asymmetric Gemini surfactants

A series of Gemini surfactants with an asymmetric structure (PKO 15-3(OH)-n; n = 12, 14 and 16) were synthesized through a simple two-step reaction consisting of a ring-opening reaction followed by a quaternization reaction. The surface tension measurements indicated that the surface activities of PKO 15-3(OH)-n were higher than those of traditional single-chain and symmetrical Gemini surfactants. The thermodynamic parameters obtained from electrical conductivity measurements showed that the micellization processes of PKO 15-3(OH)-n were spontaneous and entropy-driven. Transmission electron microscopy and dynamic light scattering measurements confirmed that PKO 15-3(OH)-n molecules with a higher asymmetric degree could form vesicles, in which surfactant molecules were interdigitated side-by-side in the vesicle membrane. The obtained results are not in accordance with those calculated from the critical packing theory, which can further complement the theory.