SnO₂ Passivation and Enhanced Perovskite Charge Extraction with a Benzylamine Hydrochloric Interlayer

Perovskite solar cells (PSCs) have gained much attention because of their expressive power conversion efficiency (PCE) of up to 25.5%. A good contact and a well-aligned energy level at the buried interfaces between electron transport layers (ETLs) and perovskite films play an essential role in promoting charge-carrier collection and suppressing nonradiative recombination. Currently, low-temperature-processed SnO₂ thin films are widely used as the ETLs to achieve efficient and stable planar PSCs. However, fabricating proper SnO₂/perovskite interfaces with a good contact and a well-aligned energy level is necessary but implies a great challenge. Herein, we modify the SnO₂ ETL using benzylamine hydrochloride (BH), which is expected to facilitate the energy level alignment and to enhance perovskite crystallization. Moreover, the BH interlayer is found to effectively reduce the trap-state density and thereby improve the charge-carrier extraction between the ETL and the perovskite layer. Consequently, the PSC with BH modification yields a higher PCE, a lower hysteresis, and better stability than the device without a BH interlayer. This study highlights the key role of molecule modification of ETLs in designing efficient and stable PSCs.