Equilibriums in Formation of Lead Halide Perovskite Nanocrystals

Physical insights related to ion equilibrium involved in the synthesis of lead halide perovskite nanocrystals remain key parameters for regulating the phase stability and luminescence intensity of these emerging materials. These have been extensively studied since the development of these nanocrystals, and different reaction processes controlling the formation of CsPbX₃ nanocrystals are largely understood. However, growth kinetics related to the formation of these nanocrystals have not been established yet. Hence, more fundamental understanding of the formation processes of these nanocrystals is urgently required. Keeping these in mind and emphasizing the most widely studied nanocrystals of CsPbBr₃, different equilibrium processes involved in their synthesis for phase and composition variations are summarized and discussed in this Perspective. In addition, implementations of these findings for shape modulations by growth are discussed, and several new directions of research for understanding more fundamental insights are also presented.