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Conformational Order of Alkyl Side Chain of Poly(3-alkylthiophene) Promotes Hole-Extraction Ability in
Chuanzhao Li1, Renlong Zhu1, Jing Lai1
1Hefei National Laboratory for Physical Sciences at the Microscale and Synergetic Innovation Center of Quantum Information & Quantum Physics, University of Science and Technology of China, Hefei, 230026, China.
Abstract:
Molecular structures of hole transport materials (HTMs) have significant impact on the optoelectronic properties of perovskite/HTM heterojunction. But the structure-property relationship in the heterojunction remains poorly understood. By using poly(3-alkylthiophene) (P3AT) as the HTM model, here we apply sum frequency generation vibrational spectroscopy to establish correlations among conformations of P3ATs, the hole extraction ability of P3ATs from the perovskite layer, and the charge mobility of P3ATs. It is revealed that with similar energy-level alignment, the conformational order of alkyl side chains in regioregular P3ATs can effectively regulate the hole extraction ability of P3ATs from perovskite layer by tuning reorganization energy. By contrast, the charge mobility of P3ATs strongly depends on the P3AT backbone's coplanarity. Our findings decouple the roles of the long-hidden conformational order of alkyl side chain and the polythiophene backbone's coplanarity on the performance of perovskite/HTM heterojunction, offering useful guidelines for boosting the performance of optoelectronic devices.
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