Improving the alkali metal electrode/inorganic solid electrolyte contact via room-temperature ultrasound solid...

The combination of alkali metal electrodes and solid-state electrolytes is considered a promising strategy to develop high-energy rechargeable batteries. However, the practical applications of these two components are hindered by the large interfacial resistance and growth of detrimental alkali metal depositions (e.g., dendrites) during cycling originated by the unsatisfactory electrode/solid electrolyte contact. To tackle these issues, we propose a room temperature ultrasound solid welding strategy to improve the contact between Na metal and Na₃Zr₂Si₂PO₁₂ (NZSP) inorganic solid electrolyte. Symmetrical Na|NZSP | Na cells assembled via ultrasonic welding show stable Na plating/stripping behavior at a current density of 0.2 mA cm^-2 and a higher critical current density (i.e., 0.6 mA cm^-2) and lower interfacial impedance than the symmetric cells assembled without the ultrasonic welding strategy. The beneficial effect of the ultrasound welding is also demonstrated in Na|NZSP | Na₃V₂(PO₄)₃ full coin cell configuration where 900 cycles at 0.1 mA cm^-2 with a capacity retention of almost 90% can be achieved at room temperature.