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Updated: Oct 10, 2025

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra
Belén Lerma-Berlanga1, Javier Castells-Gil1, Carolina R Ganivet1
1Functional Inorganic Materials Team, Instituto de Ciencia Molecular (ICMol), Universitat de València, 46980 Paterna, València, Spain.
Abstract:
Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m2·g-1.
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