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Updated: Oct 10, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Advances in allylic and benzylic C-H bond functionalization enabled by metallaphotoredox catalysis
Huifeng Yue1, Chen Zhu1, Long Huang2
1KAUST Catalysis Center, KCC, King Abdullah University of Science and Technology, KAUST, Thuwal 23955-6900, Saudi Arabia. magnus.rueping@kaust.edu.sa.
Abstract:
Metallaphoto-catalysis has been established as a robust platform for efficient construction of a range of chemical bonds. Moreover, transformation of native functionalities such as C(sp3)-H bonds to produce functional molecules represents one of the most attractive strategies in organic synthesis. Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp3)-H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.
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