Alginate/Banana Waste Beads Supported Metal Nanoparticles for Efficient Water Remediation

Water pollution is considered a perilous issue that requires an immediate solution. This is largely because of the strong correlation between the global population increase and the amount of waste produced (most notably food waste). This project prompts the conversion of food waste into useful materials that can be used with sodium alginate as a catalytic support for metal nanoparticles. Sodium alginate/banana peel (Alg/BP) beads were prepared simply using an eco-friendly method. The prepared materials were modified using nanostructured materials to enhance their characteristics. Alg/BP beads were employed as adsorbents for metals that were then treated with sodium borohydride to produce MNPs@Alg/BP. Different MNPs@Alg/BP (MNPs = Ag, Ni, Co, Fe, and Cu) were used as catalysts for reducing 4-nitrophenol (4-NP) by NaBH₄ to evaluate each catalyst performance in a model reaction. The results exhibited that Cu@Alg/BP was most efficient toward complete transformation of 4-NP. Therefore, Cu@Alg/BP was also used as a catalyst for the reduction of potassium ferricyanide, congo red, methyl orange (MO), and methylene blue. It was found that Cu@Alg/BP beads catalytically reduced up to 95-99% of above pollutants within a few minutes. Cu@Alg/BP beads were more selective in reducing MO among the pollutants. The catalytic activity of Cu@Alg/BP was examined by evaluating the impact of numerous parameters on MO reduction. The results are expected to provide a new strategy for the removal of inorganic and organic water contaminants based on efficient and low-cost catalysts.