The Influence of Hydrogen Bond Donors on the CO₂ Absorption Mechanism by the Bio-Phenol-Based Deep Eutectic Solvents

Recently, deep eutectic solvents (DESs), a new type of solvent, have been studied widely for CO₂ capture. In this work, the anion-functionalized deep eutectic solvents composed of phenol-based ionic liquids (ILs) and hydrogen bond donors (HBDs) ethylene glycol (EG) or 4-methylimidazole (4CH₃-Im) were synthesized for CO₂ capture. The phenol-based ILs used in this study were prepared from bio-derived phenols carvacrol (Car) and thymol (Thy). The CO₂ absorption capacities of the DESs were determined. The absorption mechanisms by the DESs were also studied using nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), and mass spectroscopy. Interestingly, the results indicated that CO₂ reacted with both the phenolic anions and EG, generating the phenol-based carbonates and the EG-based carbonates, when CO₂ interacted with the DESs formed by the ILs and EG. However, CO₂ only reacted with the phenolic anions when the DESs formed by the ILs and 4CH₃-Im. The results indicated that the HBDs impacted greatly on the CO₂ absorption mechanism, suggesting the mechanism can be tuned by changing the HBDs, and the different reaction pathways may be due to the steric hinderance differences of the functional groups of the HBDs.