A novel Fe-rectorite composite catalyst synergetic photoinduced peroxymonosulfate activation for efficient...

Developing a low-cost and efficient photocatalysts activated peroxymonosulfate (PMS) for organic pollutants degradation are recognized as an importance way for dealing with environmental pollution. In this work, Fe-rectorite catalyst was synthesized by a simple impregnation-calcine method to synergetic photo activate PMS for antibiotics degradation. As expected, the Fe-rectorite/PMS/Light system exhibits superior catalytic performance for tetracycline (TC) removal, which achieving 96.4% removal rate of TC (30 mg/L) under light within 60 min. Fe-retorite has better degradation performance for TC than rectorite under photo-mediation. The enhancement of the degradation performance of TC by Fe-retorite can be attributed to the improvement of the separation efficiency of photogenerated electrons and holes in the rectorite by the loading of Fe₂O₃, and the accelerated active Fe(Ⅱ)/Fe(Ⅲ) cycle on the surface under photo-mediation. The large specific surface area and abundant hydroxyl groups of rectorite can also provide active sites for PMS activation. The quenching experiment and electron paramagnetic resonance (EPR) test were indicated that the h⁺, SO₄•^-, •OH, and O₂^-• all contributed to TC degradation. And the possible degradation pathway was proposed by LC-MS. This work helps induced a novel direction that design green, efficient, and recyclable heterogeneous catalysts to synergetic photoinduced PMS activation for enhanced degradation of TC.