Construction of NiCoZnS materials with controllable morphology for high-performance supercapacitors

A facile two-step hydrothermal approach with post-sulfurization treatment was put forward to construct the mixed transition metal sulfide (NiCoZnS) with a high electrochemical performance. The different morphologies of NiCoZnS materials were successfully fabricated by adjusted the Ni/Co molar ratio of the NiCoZn(OH)F precursor. Moreover, thein situphase transformation from the NiCoZn(OH)F phase to Zn_0.76Co_0.24S and NiCo₂S₄phases and lattice defects via the S^2-ion-exchange were determined by x-ray diffractometer, transmission electron microscopy and x-ray photoelectron spectroscopy techniques, which improved electric conductivity and interfacial active sites of the NiCoZnS, and so promoted the reaction kinetics. Significantly, the urchin-like NiCoZnS_1/1prepared at the Ni/Co molar ratio of 1.0 exhibited promising electrochemical performances with high capacitance and excellent cycling stability. Furthermore, the asymmetric device (NiCoZnS//AC) using NiCoZnS_1/1as the positive electrode had excellent supercapacitor performances with an energy density of 57.8 Wh·kg^-1at a power density of 750 W·kg^-1as well as a long cycle life (79.2% capacity retention after 10 000 cycles), indicating the potential application in high-performance supercapacitors.