Custom Synthesis of ZnO Nanowires for Efficient Ambient Air-Processed Solar Cells

Nanostructuration of solar cells is an interesting approach to improve the photovoltaic conversion efficiency (PCE). This work aims at developing architectured 3D hybrid photovoltaic solar cells using ZnO nanowires (ZnONWs) as the electron transport layer (ETL) and nanocollectors of electrons within the active layer (AL). ZnONWs have been synthesized using a hydrothermal process with a meticulous control of the morphology. The AL of solar cells is elaborated using ZnONWs interpenetrated with a bulk heterojunction composed of donor (π-conjugate low band gap polymer: PBDD4T-2F)/acceptor (fullerene derivate: PC₇₁BM) materials. An ideal interpenetrating ZnONW-D/A system with predefined specific morphological characteristics (length, diameter, and inter-ZnONW distances) was designed and successfully realized. The 3D architectures based on dense ZnONW arrays covered with conformal coatings of AL result in an increased amount of the ETL/AL interface, enhanced light absorption, and improved charge collection efficiency. For AL/ZnONW assembly, spin-coating at 100 °C was found to be the best. Other parameters were also optimized such as the D/A ratio and the pre/post-treatments achieving the optimal device with a D/A ratio of 1.25/1 and methanol treated on ZnONWs before and after the deposition of AL. A PCE of 7.7% (1.4 times better than that of the 2D cells) is achieved. The improvement of the performances with the 3D architecture results from both of: (i) the enhancement of the ZnO/AL surface interface (1 μm²/μm² for the 2D structure to 6.6 μm²/μm² for the 3D architecture), (ii) the presence of ZnONWs inside the AL, which behave as numerous nanocollectors (∼60 ZnONW/μm²) of electrons in the depth of the AL. This result validates the efficiency of the concept of nanotexturing of substrates, the method of solar cell assembly based on the nano-textured surface, the chosen morphological characteristics of the nanotexture, and the selected photoactive organic materials.