Methane emission dynamics from a Danish landfill: The effect of changes in barometric pressure

This study investigates temporal variability on landfill methane (CH₄) emissions from an old abandoned Danish landfill, caused by the rate of changes in barometric pressure. Two different emission quantification techniques, namely the dynamic tracer dispersion method (TDM) and the eddy covariance method (EC), were applied simultaneously and their results compared. The results showed a large spatial and temporal CH₄ emission variation ranging from 0 to 100 kg h^-1 and 0 to 12 μmol m^-2 s^-1, respectively. Landfill CH₄ emissions dynamics were influenced by two environmental factors: the rate of change in barometric pressure (a strong negative correlation) and wind speed (a weak positive correlation). The relationship between CH₄ emissions and the rate of change in barometric pressure was more complicated than a linear one, thereby making it difficult to estimate accurately annual CH₄ emissions from a landfill based on discrete measurements. Furthermore, the results did not show any clear relationship between CH₄ emissions and ambient temperature. Large seasonal variations were identified by the two methods, whereas no diurnal variability was observed throughout the investigated period. CH₄ fluxes measured with the EC method were strongly correlated with emissions from the TDM method, even though no direct relationship could be established, due to the different sampling ranges of the two methods and the spatial heterogeneity of CH₄ emissions.