Non-noble Nickel-Modified Covalent Organic Framework for Partial Hydrogenation of Aromatic Terminal Alkynes

Developing non-noble metal-based catalysts with excellent performance for selective hydrogenation of alkynes under mild reaction conditions is highly desirable but still faces challenges. Herein, a non-noble nickel-modified covalent organic framework (Ni/COF) had been synthesized through a facile post-modified method and followed by reduction at a different temperature under a H₂/Ar atmosphere. The as-prepared catalysts were characterized by X-ray diffraction, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller, and Fourier transforms infrared, and the optimal H₃₅₀-Ni/COF presents excellent catalytic performance in the semihydrogenation of a series of aromatic terminal alkyne substrates, particularly in the partial hydrogenation of phenylacetylene with nearly full conversion and 85% selectivity toward styrene under mild reaction conditions (10 bar of H₂, 100 °C, and 1 h). Moreover, such a catalyst also exhibited satisfying stability after three consecutive cycles.