IrO_x Nanoclusters Modified by BaCO₃ Enable ″Two Birds with One Stone″ in Solar-Driven Direct Unbuffered Seawater...

Direct seawater electrolysis (DSE) coupled with renewable energy can maximize the sustainability of hydrogen energy acquisition by effectively alleviating the dependence on pure water resources. In a practical sense, the parallel chlorine evolution reaction (CER) of DSE opens up an opportunity to hit ″two birds with one stone″ by the dual values of anode and cathode. However, the biggest challenge is how to control the selectivity of CER to balance its values and drawbacks. Here, we use the different nucleation rates of iridium and barium ions in a weak basic solution and subsequent acid etching to devise an IrO_x nanocluster (IrO_x-Cs) supported BaCO₃. The catalyst-support interaction between IrO_x-Cs and BaCO₃ enables repelling the Cl^- near the electrode interface layer to achieve a controlled CER selectivity. Additionally, the mass activity of the prepared IrO_x-Cs@BaCO₃ is as high as 1402 A g^-1_Ir, which is 7.12 times higher than that of IrO₂ oxides in unbuffered seawater. The photovoltaic-electrolysis device paired by IrO_x-Cs@BaCO₃ with controlled CER activity and Pt demonstrated that valuable active chlorine and H₂ can be simultaneously obtained, with the flexibility to bind to different ion exchange membranes.