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First Study on Nihonium (Nh, Element 113) Chemistry at TASCA
A Yakushev1,2, L Lens1,3, Ch E Düllmann1,2,3
1GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt, Germany.
Frontiers in Chemistry
|December 17, 2021
Summary
Nihonium (Nh) atoms exhibit higher chemical reactivity than flerovium (Fl) atoms, as confirmed by initial gas-phase chemistry experiments. Advanced detection systems are needed for further studies of these superheavy elements.
Area of Science:
- Nuclear Physics
- Quantum Chemistry
- Radiochemistry
Background:
- Nihonium (Nh, element 113) and flerovium (Fl, element 114) are superheavy elements with occupied 7p electron shells.
- Relativistic effects significantly influence the electronic structure and predicted chemical properties of these elements.
- Flerovium is predicted to be inert due to a stabilized closed 7p sub-shell, while Nihonium's reactivity is expected due to an unpaired 7p electron.
Purpose of the Study:
- To investigate the chemical reactivity of Nihonium (Nh) in the gas phase.
- To compare the experimentally observed reactivity of Nh with theoretical predictions and with its neighbor Flerovium (Fl).
- To assess the feasibility of studying Nh chemistry using newly developed experimental setups.
Main Methods:
- Theoretical calculations of Nh reactivity.
- Gas-phase chemical studies of Nh.
- Experimental testing of the miniCOMPACT detection device using Francium (Fr) isotopes.
Main Results:
- Experimental observations indicate that Nihonium (Nh) atoms are more chemically reactive than Flerovium (Fl) atoms.
- The findings align with theoretical expectations of Nh's higher reactivity.
- Initial tests of the miniCOMPACT detector with Francium (Fr) suggest its suitability for future Nh studies.
Conclusions:
- Nihonium (Nh) demonstrates higher chemical reactivity compared to Flerovium (Fl).
- Advanced experimental setups are necessary for effective chemical studies of Nihonium.
- The miniCOMPACT detector shows promise for future investigations into the chemistry of superheavy elements like Nihonium.
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