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A Photoorganizable Triple Shape Memory Polymer for Deployable Devices.

Jiahao Sun1, Bo Peng1, Yao Lu1

  • 1Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai, 200433, China.

Small (Weinheim an Der Bergstrasse, Germany)
|December 17, 2021
PubMed
Summary
This summary is machine-generated.

Researchers developed a novel photoorganizable triple shape memory polymer (POTSMP) for aerospace applications. This smart material enables programmable deformation, in situ repair, and complex 3D structure manufacturing using light stimuli.

Keywords:
azobenzene-containing polymerslight reconfigurationphotoorganizable performancesmart deployable structurestriple shape memory

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Aerospace Engineering

Background:

  • Stimuli-responsive materials offer potential for advanced deployable devices in aerospace.
  • Current smart materials often lack in situ repair capabilities and complex shape programmability.

Purpose of the Study:

  • To develop a novel photoorganizable triple shape memory polymer (POTSMP) for aerospace applications.
  • To achieve remote-controlled programmable deformation and in situ repair using light stimuli.

Main Methods:

  • Synthesis of an azobenzene-containing thermoplastic polyurethane as the POTSMP.
  • Utilizing UV and visible light illumination for shape programming and recovery.
  • Employing UV irradiation for rapid light-reconfiguration, including light-reshaping and light-welding.

Main Results:

  • The POTSMP demonstrated arbitrary programming of two temporary shapes and precise, stepwise shape recovery.
  • Rapid light-reconfiguration (reshaping and welding) was achieved in seconds via UV irradiation.
  • Facile manufacturing of complex 2D/3D structures without specialized molds was enabled.

Conclusions:

  • The developed POTSMP offers versatile photoresponsive capabilities for smart deployable devices.
  • This material facilitates in situ repair and complex structure fabrication, extending device service life.
  • POTSMP shows significant potential for advancing photoresponsive triple shape memory polymers in aerospace.