Efficient removal of plastic additives by sunlight active titanium dioxide decorated Cd-Mg ferrite nanocomposite:...

Large use of flame retardants or additives in plastic industries have caused scientific attention as their leaching from consumer products is indicative of environmental concern. Moreover, plastic additives have proven features of endocrine disruptors, genotoxicity and persistence. Therefore, photodegradation of tetrabromobisphenol A (TBBPA) and bisphenol A (BPA) were explored in water. Seeing environmental safety, titanium dioxide decorated magnesium substituted cadmium ferrite (CdMgFe₂O₄@TiO₂) was synthesized by using plant extract of M. koenigii via co-precipitation. Sharp peaks obtained in PXRD ensured high crystallinity and purity of distorted spherical nanocomposite (5-25 nm). Subsequently, CdMgFe₂O₄@TiO₂ nanocatalyst was evaluated for the effective elimination of plastic additives at variable reaction parameters (pollutant: 2-10 mgL^-1; catalyst: 5-25 mg; pH: 3-7, dark-sunlight). With 20 mg of catalytic dose, CdMgFe₂O₄@TiO₂ showed maximum degradation of 2 mgL^-1 of TBBPA (91%) and BPA (94%) at neutral pH under sunlight. Considerable reduction in persistence of TBBPA (t_1/2:2.4 h) and BPA (t_1/2:2.1 h) indicated admirable photoactivity of CdMgFe₂O₄@TiO₂. Results were supported by BET, zeta potential, band reflectance and photoluminescence analysis that indicated for higher surface area (90 m²g^-1), larger particle stability (-20 mV), lower band gap (1.9 eV) and inhibited charge-pairs recombination in nanocomposite. Degradation consisted of initial Langmuir-adsorption followed by first order kinetics. Scavenger analysis revealed the role of hydroxyl radical in photodegradation studies. Nanocomposite was effective up to eight cycles without any significant loss of activity that advocated its high-sustainability and cost-effectiveness. Overall, with excellent surface characteristics, green synthesized CdMgFe₂O₄@TiO₂ nanocomposite is a promising and alternative photocatalyst for industrial applications.