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Updated: Oct 9, 2025
Focused Ion Beam Fabrication of LiPON-based Solid-state Lithium-ion Nanobatteries for In Situ Testing
Published on: March 7, 2018
High Performance Single-Crystal Ni-Rich Cathode Modification via Crystalline LLTO Nanocoating for All-Solid-State
Zhaoze Fan1, Jiayuan Xiang2,3, Qiong Yu4
1State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China.
Abstract:
Sulfide-based all-solid-state lithium batteries (ASSLBs) assembled with Ni-rich layered cathodes are currently promising candidates for achieving high-energy-density and high-safety energy storage systems. However, the interfacial challenges between sulfide electrolyte and Ni-rich layered cathode, such as space charge layer, side reaction, and poor physical contact, greatly limit the practicality of all-solid-state batteries. In this work, an optimal crystalline Li0.35La0.55TiO3 (LLTO) surface coating with a thickness of roughly 6 nm and a high Li ion conductivity of 0.3 mS cm-1 was adopted to enhance the structural stability of the single-crystal LiNi0.6Co0.2Mn0.2O2 (S-NCM622) cathode in ASSLBs. Furthermore, due to the high ionic conductivity and chemical stability of the LLTO coating layer, the interfacial problems, involving interfacial reaction and a space charge layer, in sulfide-based all-solid-state batteries have been effectively solved. As a result, the assembled ASSLBs with the S-NCM622@LLTO cathode exhibit high initial capacity (179.7 mAh g-1) at 0.05 C and excellent cycling performance with 84.5% capacity retention after 100 cycles at 0.1 C at room temperature. This work proposes an effective strategy to enhance the performance of Ni-rich layered cathodes for next-generation high-energy-density sulfide-based lithium batteries.
