Machine learning-assisted ammonium detection using zinc oxide/multi-walled carbon nanotube composite based impedance...

We report a machine learning approach to accurately correlate the impedance variations in zinc oxide/multi walled carbon nanotube nanocomposite (F-MWCNT/ZnO-NFs) to NH₄⁺ ions concentrations. Impedance response of F-MWCNT/ZnO-NFs nanocomposites with varying ZnO:MWCNT compositions were evaluated for its sensitivity and selectivity to NH₄⁺ ions in the presence of structurally similar analytes. A decision-making model was built, trained and tested using important features of the impedance response of F-MWCNT/ZnO-NF to varying NH₄⁺ concentrations. Different algorithms such as kNN, random forest, neural network, Naïve Bayes and logistic regression are compared and discussed. ML analysis have led to identify the most prominent features of an impedance spectrum that can be used as the ML predictors to estimate the real concentration of NH₄⁺ ion levels. The proposed NH₄⁺ sensor along with the decision-making model can identify and operate at specific operating frequencies to continuously collect the most relevant information from a system.