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Updated: Oct 9, 2025
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Response to the Temperature and Solvent Stimulation of MOF Material in a Single-Crystal to Single-Crystal Manner
Jian-Lei Qian1, Tao Zhou1, Xin Lu1
1AnHui Province Key Laboratory of Optoelectronic and Magnetism Functional Materials, Key Laboratory of Functional Coordination Compounds of Anhui Higher Education Institutes, Anqing Normal University, Anqing 246133, P. R. China.
Abstract:
Under solvothermal conditions, a three-dimensional mononuclear crystal AQNU-1, {[Co(H2L)(DPD)(H2O)2]·2DMA} (H2L = 5-(bis(4-carboxybenzyl)amino)isophthalic acid, DPD = 4,4'-(2,5-diethoxy-1,4-phenylene)dipyridine) has been synthesized. The transformations of AQNU-1 to binuclear {[Co2(L)(DPD)1.5(H2O)3]·DMA·H2O} (AQNU-2) and pentanuclear {[Co5(L)2(DPD)2(OH)2]·2H2O} (AQNU-3) were realized by double stimulation of temperature and solvent, which were accomplished by single-crystal to single-crystal (SC-SC) reaction.
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