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Updated: Oct 9, 2025

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene
Published on: May 20, 2019
Polymerizations with Elemental Sulfur: From Petroleum Refining to Polymeric Materials
Taeheon Lee1, Philip T Dirlam2, Jon T Njardarson1
1Department of Chemistry and Biochemistry, University of Arizona, Tucson, Arizona 85721, United States.
Abstract:
The production of elemental sulfur from petroleum refining has created a technological opportunity to increase the valorization of elemental sulfur by the synthesis of high-performance sulfur-based plastics with improved optical, electrochemical, and mechanical properties aimed at applications in thermal imaging, energy storage, self-healable materials, and separation science. In this Perspective, we discuss efforts in the past decade that have revived this area of organosulfur and polymer chemistry to afford a new class of high-sulfur-content polymers prepared from the polymerization of liquid sulfur with unsaturated monomers, termed inverse vulcanization.
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